Rh(1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)(COD) tetrafluoroborate, an unsymmetrical Rh-homoazallylcarbene: synthesis, X-ray structure and reactivity in carbonyl arylation and hydrosilylation reactions

The synthesis of novel Rh(1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)(COD) tetrafluoroborate (1, COD = η4-1,5-cyclooctadiene) is described. The N-heterocyclic carbene acts as a bidentate ligand with the carbene coordinating to the Rh(I) center and an arene group acting as a homoazallyl ligand. 1 was used in various carbonyl arylation and hydrosilylation reactions allowing the formation of the desired products with unprecedented selectivity and efficiency. Thus, turn-over numbers (TONs) up to 2000 were achieved.

Graphical abstractNovel Rh(1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene) (η4-1,5-cyclooctadiene) tetrafluoroborate was prepared and used in carbonyl arylation and hydrosilylation reactions allowing turn-over numbers up to 2000.Figure optionsDownload full-size imageDownload as PowerPoint slide