| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1324116 | Journal of Organometallic Chemistry | 2010 | 7 Pages |
Abstract
The reaction of mono- and disubstituted alkynes with CH2I2-R3Al (R = Me, Et, i-Bu) was studied. It was found that the reaction of alkynes with CH2I2 in the presence of Me3Al gives β-iodoethyl-substituted cyclopropanes. The use of Et3Al or i-Bu3Al affords exclusively cyclopropylic organoaluminum compounds.
Graphical abstractReaction of alkynes with CH2I2 in the presence of Me3Al gives β-iodoethyl-substituted cyclopropanes. The use of Et3Al or i-Bu3Al affords exclusively cyclopropylic organoaluminum compounds.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ilfir R. Ramazanov, Leisan K. Dil’mukhametova, Usein M. Dzhemilev, Oleg M. Nefedov,