| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1324173 | Journal of Organometallic Chemistry | 2005 | 7 Pages |
Abstract
The ionic complex [Ga{N(SPiPr2)(SePiPr2)-S, Se}2]+[GaCl4]â (5) was prepared by means of a redistribution reaction from the mono-chelate [Cl2Ga{N(SPiPr2)(SePiPr2)-S, Se}] (3) complex in benzene. A similar phenomenon occurs in the heavier indium homologues, where the neutral complexes [ClIn{N(SPiPr2)(SePiPr2)-S, Se}2] (7) and [ClIn{N(OPiPr2)(SPiPr2)-O, S}2] (8) were isolated along with InCl3 as the main reaction by-product.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mónica Moya-Cabrera, Raymundo Cea-Olivares, Jocelyn Alcántara-GarcÃa, Rubén A. Toscano, Vojtech Jancik, Verónica GarcÃa-Montalvo, Simón Hernández-Ortega,