| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1324177 | Journal of Organometallic Chemistry | 2005 | 4 Pages |
Abstract
The hydroformylation of medium-chain C6 olefins and of allyl alcohol was achieved with paraformaldehyde in dioxane solution using rhodium catalysts with mono-, bi-, and tri-dentate phosphine ligands. The highest activities with n/i ratios around 2, were obtained for a system derived from [Rh(dppe)2]+, prepared in situ by reaction of Rh(acac)(CO)2 with 2 eq of dppe.
Graphical abstractHydroformylation of C6 alkenes and allyl alcohol has been achieved by reaction with formaldehyde in the presence of Rh(acac)(CO)2 + 2eq dppe and other Rh-phosphine catalysts under moderate reaction conditions..Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
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Authors
Merlin Rosales, Angel González, Beatríz González, Cristhina Moratinos, Homero Pérez, Johán Urdaneta, Roberto A. Sánchez-Delgado,