| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1324338 | Journal of Organometallic Chemistry | 2014 | 7 Pages |
Abstract
We analyzed the nature of M-PNR2 bonds in the terminal cationic phosphinidene complexes of manganese and rhenium [(CO)5M-PNR2]+ (RÂ =Â Me, iPr, tBu) and [(PMe3)(CO)4M-PNiPr2]+. The contribution of dispersion interactions is large in computing accurate bond dissociation energies between the interacting metal fragments [(CO)5M]+ and ligand fragments [PNR2].
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Accurate theoretical description of the M-PNR2 bonds in phosphinidene complexes of manganese and rhenium [(CO)5M-PNR2]+ (R = Me, iPr, tBu) and [(PMe3)(CO)4M-PNiPr2]+: A DFT-D3 study](/preview/png/1324338.png "First Page Preview: Accurate theoretical description of the M-PNR2 bonds in phosphinidene complexes of manganese and rhenium [(CO)5M-PNR2]+ (R = Me, iPr, tBu) and [(PMe3)(CO)4M-PNiPr2]+: A DFT-D3 study")
Authors
Krishna K. Pandey, Pradeep Tiwari, Pankaj Patidar, Sunil K. Patidar, Ravi Vishwakarma, Pankaj K. Bariya,