Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1324339 | Journal of Organometallic Chemistry | 2014 | 4 Pages |
•Compound 2 contains a spiro-centered aluminum atom where the inorganic AlB2O3 ring is fused to the organic C3N2 part.•We report on an eight-membered boroxine-linked dialuminum compound 3.•The mechanism explains the possible formation of compound 3.
The reaction of LAlH2 (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) (1) with cyclopentylboronic acid resulted in the boroxine-linked aluminum compound LAl[OB(C5H9)]2(μ-O) (2). However, the reaction of 1 with 3-hydroxymethylphenylboronic acid gave an eight-membered boroxine-linked dialuminum compound of composition [LAlOB(3-OHCH2C6H4)]2 (3) with a spiro center at each of the aluminum atoms. The two complexes were characterized by 1H NMR, IR spectroscopy, elemental analysis, and single crystal X-ray structural analysis.
Graphical abstractThe reaction of LAlH2 (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) (1) with cyclopentylboronic acid resulted in the boroxine-linked aluminum compound LAl[OB(C5H9)]2(μ-O) (2). However, the reaction of 1 with 3-hydroxymethylphenylboronic acid gave an eight-membered boroxine-linked dialuminum compound of composition [LAlOB(3-OHCH2C6H4)]2 (3) with a spiro center at each of the aluminum atoms.Figure optionsDownload full-size imageDownload as PowerPoint slide