Reaction of secondary phosphine selenides with the system Se/MOH (M = Li, Na, K, Rb, Cs): A novel three-component synthesis of diorganodiselenophosphinates

Secondary phosphine selenides, R2P(Se)H (R = PhCH2CH2, PhCH(Me)CH2, 4-t-BuC6H4CH2CH2, NaphthylCH2CH2, Ph), react with the system Se/MOH (M = Li, Na, K, Rb, Cs) in the system THF/EtOH at ambient temperature unusually fast (20–30 s) to give cleanly and almost quantitatively (in 94–100% yield) earlier unknown diorganodiselenophosphinates of alkali metals.

Graphical abstractSecondary phosphine selenides, R2P(Se)H (R = PhCH2CH2, PhCH(Me)CH2, 4-t-BuC6H4CH2CH2, NaphthylCH2CH2, Ph), react with the system Se/MOH (M = Li, Na, K, Rb, Cs) in the system THF/EtOH at ambient temperature unusually fast (20–30 s) to give cleanly and almost quantitatively (94–100% yield) earlier unknown diorganodiselenophosphinates of alkali metals.Figure optionsDownload full-size imageDownload as PowerPoint slide