| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1324395 | Journal of Organometallic Chemistry | 2013 | 7 Pages |
•New synthesis route leading to saturated NHC ligands functionalized in the 4-position of the backbone.•Synthesis and characterization of the derived pyridine coordinated NHC–Pd(Cl(II) complex.•Structural elucidation of the imidazolinium salt and the palladium complex.
The synthesis and characterization of a novel pyridine coordinated dichloridopalladium(II) NHC complex is described. This compound possesses a saturated NHC ligand that is substituted with a para-nitrophenyl function in the 4-position of the NHC backbone. It is accessible in four steps with overall good yields starting from 4-nitro acetophenone.
Graphical abstractThe pyridine coordinated dichloridopalladium(II) NHC complex is accessible in five steps in good yields from cheap para-nitrophenyl.Figure optionsDownload full-size imageDownload as PowerPoint slide
