Article ID Journal Published Year Pages File Type
1324626 Journal of Organometallic Chemistry 2016 11 Pages PDF
Abstract

•Ag, Ni–NHCs were synthesized and characterized by elemental analysis, NMR and X-ray diffraction.•Complexes 5 and 6 formed 1D and 2D supramolecular chains.•Complex 7 afford the dinuclear Ag metallamacrocycles.•Complex 4 exhibits moderate catalytic activity in the Suzuki−Miyaura cross-coupling reaction.

The imidazolium salts [(N-alkyl-imidazolyl) methyl] benzotriazole hexafluorophosphate (L1H: alkyl = n-C4H9, L2H: alkyl = picoly, L3H: alkyl = 9-anthrylmethyl, L4H: alkyl = 1-naphthylmethyl) have been prepared. Mononuclear N-Heterocyclic carbene silver complexes: L1AgPF6 (1), L2AgPF6 (2), L3AgPF6 (3) were synthesized in DMSO. Transmetalation reactions afford the synthesis of the nickel(II) complex L2Ni(PF6)2 (4). Furthermore, L2H, L3H and L4H were treated with silver oxide in CH3CN to afford other complexes (5, 6 and 7). The complexes 5 and 6 formed 1D and 2D supramolecular chains by AgN bond and intermolecular π-π interactions, respectively, which were found that the carbene carbon atoms of NHCs are not coordinated to silver atom. However, in Complex 7, silver atoms selectly bind to nitrogen atoms of benzotriazoles and carbon atoms of imidazoles, which afford the dinuclear Ag metallamacrocycles. Complexes 1–7 were characterized by single crystal X-ray diffraction, NMR spectroscopy, elemental analysis and powder X-ray diffraction. The catalytic activity of NHCNi complex 4 for Suzuki−Miyaura cross-coupling was studied.

Graphical abstractTreatment of L4H with Ag2O in CH3CN under exclusion of light at 50 °C for 24 h resulted in the formation of the complexes 7. In Complex 7, silver atoms selectly bind to nitrogen atoms of benzotriazoles and carbon atoms of imidazoles, which afford the dinuclear Ag metallamacrocycles.Figure optionsDownload full-size imageDownload as PowerPoint slide

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Physical Sciences and Engineering Chemistry Inorganic Chemistry
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