Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1324648 | Journal of Organometallic Chemistry | 2009 | 5 Pages |
The title compounds 3 and 4 were synthesized by reaction of 1,1′ ferrocenylenediol with the Co triple decker compounds [{(η5-Me5C5)Co}2(η6:η6-toluene)] and [{(η5-EtMe4C5)Co}2(η6:η6-toluene)], respectively. The central Co atom of 3 is coordinated by five O atoms in a square-pyramidal manner. The remaining two Co atoms of 3 are coordinated to a Me5C5 ligand in a η5-fashion and by the two O atoms of two 1,1′ ferrocenylenediolato ligands which serve as chelating ligands. In 4, the central Co atom is coordinated to all six O atoms of three ferrocenylenediolato ligands in a trigonal-prismatic manner, whereas the two other Co atoms are coordinated by an EtMe4C5 ligand in a η5-fashion and by three O atoms of three ferrocenylenediolato ligands resulting in an overall tripoidal structure for 4.
Graphical abstractReaction of the triple decker complexes [{(η5-Me5C5)Co}2(η6:η6-toluene)] (1) and [{(η5-EtMe4C5)Co}2(η6:η6-toluene)] (2) with 1,1′ ferrocenylenediol in different ratios in ether at room temperature leads to the title compounds 3A and 4, respectively, in good yields. In 3 and 4 the central Co atoms are coordinated in a rather rare square-pyramidal (3) and trigonal-prismatic coordination (4) geometry, respectively.Figure optionsDownload full-size imageDownload as PowerPoint slide