Article ID Journal Published Year Pages File Type
1324879 Journal of Organometallic Chemistry 2011 5 Pages PDF
Abstract

A general catalytic system for the decarbonylative addition reaction of aldehydes with alkynes is developed by using an iridium catalyst system. Both aromatic and aliphatic aldehydes reacted with terminal alkynes efficiently to give the corresponding olefination products in high yields and up to 11:1 E/Z selectivity.

Graphical abstractA general catalytic system for the decarbonylative addition reaction of aldehydes with alkynes is developed by using an iridium catalyst system. Both aromatic and aliphatic aldehydes reacted with terminal alkynes efficiently to give the corresponding olefination products in high yields and up to 11:1 E/Z selectivity.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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