| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1324888 | Journal of Organometallic Chemistry | 2011 | 9 Pages |
Abstract
A direct intermolecular addition of nitrogen and 1,3-dicarbonyl nucleophiles to stabilized double bonds (styrenes, 1,3-dienes, enol-ethers, sugars.) in the presence of green and inexpensive FeCl3 catalyst is described.
Graphical abstractDirect intermolecular addition of nitrogen and 1,3-dicarbonyl nucleophiles to stabilized double bonds (styrenes, 1,3-dienes, enol-ethers, sugars.) in the presence of green and inexpensive FeCl3 catalyst.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► FeCl3 is a cheap, abundant and non-toxic complex. ► Hydroaminations ( and additions of 1,3-dicarbonyl nucleophiles) are 100% atom-economic reactions. ► Electronic effects in the hydroamination are highlighted.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Christophe Dal Zotto, Julien Michaux, Araceli Zarate-Ruiz, Eric Gayon, David Virieux, Jean-Marc Campagne, Vincent Terrasson, Grégory Pieters, Anne Gaucher, Damien Prim,