2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl transition metal (Fe, Co, and Ni) dichlorides: Syntheses, characterizations and their catalytic behaviors toward ethylene reactivity

A series of 2-(1-isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl metal complexes [iron (II) (1a–6a), cobalt (II) (1b–6b) and nickel (II) (1c–6c)] were synthesized and fully characterized by elemental and spectroscopic analyses. Single-crystal X-ray diffraction analyses of five coordinated complexes 5a, 3b, 5b, 1c and 2c reveal 5a and 5b as distorted trigonal-bipyramidal geometry, and 3b, 1c and 2c as distorted square pyramidal geometry. All complexes performed ethylene reactivity with the assistance of various organoaluminums. The iron complexes displayed good activities in the presence of MAO and MMAO. Upon activated by Et2AlCl, the cobalt analogues showed moderate ethylene reactivity, while the nickel analogues exhibited relatively higher activities.

Graphical abstractA series of 2-(1-isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl metal complexes [iron(II) (1a–6a), cobalt(II) (1b–6b) and nickel(II) (1c–6c)] were synthesized and fully characterized by elemental and spectroscopic analyses. Single-crystal X-ray diffraction analyses of five coordinated complexes 5a, 3b, 5b, 1c and 2c reveal 5a and 5b as distorted trigonal-bipyramidal geometry, and 3b, 1c and 2c as distorted square pyramidal geometry. All complexes performed ethylene oligomerization with the assistance of various organoaluminums. The iron complexes displayed good activity in the presence of MAO and MMAO. Upon activated by Et2AlCl, the cobalt analogues showed moderate ethylene reactivity, while the nickel analogues exhibited relatively higher activity.Figure optionsDownload full-size imageDownload as PowerPoint slide