| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1324999 | Journal of Organometallic Chemistry | 2010 | 9 Pages |
Abstract
The PESs of systems including deactivated silylenes (SiHHal, SiHal2, Hal = F, Cl, and 2-silaimidazol-2-ylidene) and buta-1,3-diene have been studied using G3(MP2)//B3LYP method. The (2 + 1) and (4 + 1) cycloaddition reactions, leading to 2-vinylsiliranes and silacyclopent-3-enes, respectively, as well as [1,3]-sigmatropic rearrangements between 2-vinylsiliranes and silacyclopent-3-enes have been considered.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
S.S. Rynin, V.I. Faustov, S.E. Boganov, M.P. Egorov, O.M. Nefedov,