Article ID Journal Published Year Pages File Type
1325058 Journal of Organometallic Chemistry 2007 6 Pages PDF
Abstract

An efficient method for the addition of trimethylsilyl cyanide (TMSCN) to various aldehydes and ketones has been described using Fe(Cp)2PF6 (2.5 mol%) as a catalyst under solvent free condition. Excellent yields of trimethylsilylether of cyanohydrin up to (94%) was achieved within 10 min.

Graphical abstractThe addition of trimethylsilyl cyanide (TMSCN) to various aldehydes and ketones catalyzed by 2.5 mol% Fe(Cp)2PF6 as a catalyst was carried out under solvent free condition. Excellent yields of trimethylsilylether of cyanohydrin (65–94%) was achieved within 10 min.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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