| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325111 | Journal of Organometallic Chemistry | 2011 | 6 Pages |
Abstract
⺠Dimerization or trimerization of CH3CN has been observed during the hydrogermolysis reaction. ⺠This provides the free amines or germanes containing these amines as ligands. ⺠Two new germanes with the conjugate bases of di- and triacetonitrile as ligands have been prepared and structurally characterized. ⺠The pathway for the reaction R3GeCH2CN with CH3CN to provide di- and triacetonitrile-substituted germanes has been elucidated.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Reactivity of α-germyl nitriles with acetonitrile: Synthesis, structures, and generation of Ph3Ge[NHC(CH3)CHCN] and 2,6-dimethyl-4-(triphenylgermylamino)pyrimidine from Ph3GeCH2CN](/preview/png/1325111.png "First Page Preview: Reactivity of α-germyl nitriles with acetonitrile: Synthesis, structures, and generation of Ph3Ge[NHC(CH3)CHCN] and 2,6-dimethyl-4-(triphenylgermylamino)pyrimidine from Ph3GeCH2CN")
Authors
Christian R. Samanamu, Arnold L. Rheingold, Charles S. Weinert,