| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325246 | Journal of Organometallic Chemistry | 2009 | 9 Pages |
Abstract
ArSeSP(S)R2 [Ar = Ph, R = Ph (1), OPri (2); 2-[MeN(CH2CH2)2NCH2]C6H4, R = Ph (3), OPri (4); 2-[O(CH2CH2)2NCH2]C6H4, R = Ph(5), OPri (6)] were investigated by solution NMR and the structures of 1, 3, 4 and 6 were established by single-crystal X-ray diffraction. In 3, 4 and 6 a C,N-ligand prevents any intra- or intermolecular Seâ¯S interactions and a T-shaped (C,N)SeS core is achieved.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Organoselenium(II) complexes containing organophosphorus ligands. Crystal and molecular structure of PhSeSP(S)Ph2, [2-{MeN(CH2CH2)2NCH2}C6H4]SeSP(S)Râ²2 (Râ²Â = Ph, OPri) and [2-{O(CH2CH2)2NCH2}C6H4]SeSP(S)(OPri)2](/preview/png/1325246.png "First Page Preview: Organoselenium(II) complexes containing organophosphorus ligands. Crystal and molecular structure of PhSeSP(S)Ph2, [2-{MeN(CH2CH2)2NCH2}C6H4]SeSP(S)Râ²2 (Râ²Â = Ph, OPri) and [2-{O(CH2CH2)2NCH2}C6H4]SeSP(S)(OPri)2")
Authors
Anca Beleaga, Monika Kulcsar, Calin Deleanu, Alina Nicolescu, Cristian Silvestru, Anca Silvestru,