| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325266 | Journal of Organometallic Chemistry | 2009 | 6 Pages |
Abstract
Interaction of palladium carbonyl carboxylates of general composition Pd6(CO)6(RCOO)6 with gaseous nitrogen monoxide was investigated. These cluster compounds were found to promote NO disproportionation into N2 and NO2 under mild conditions. The process results in the formation of unusual eight-nuclear palladium carboxylate clusters Pd8(CO)4(NO2)4(RCOO)8.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Interaction of polynuclear palladium (I) carbonyl carboxylates with gaseous NO: X-ray structure of eight-nuclear clusters Pd8(μ-CO)4(μ-OOCR)4[μ-N(O)O-]4](/preview/png/1325266.png "First Page Preview: Interaction of polynuclear palladium (I) carbonyl carboxylates with gaseous NO: X-ray structure of eight-nuclear clusters Pd8(μ-CO)4(μ-OOCR)4[μ-N(O)O-]4")
Authors
Oleg N. Shishilov, Tatiana A. Stromnova, Andrei V. Churakov, Lyudmila G. Kuz'mina, Judith A.K. Howard,