| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325305 | Journal of Organometallic Chemistry | 2007 | 11 Pages |
Abstract
The reaction of potassium hexamethyldisilazide with N(Diep)C(H)NH(Diep) (DiepFormH, Diep = 2,6-Et2C6H3) in THF yields the half deprotonated compound [K(DiepForm)(DiepFormH)] (1), which exhibits suppressed reactivity with the hexamethyldisilazide anion. Reaction of 1 with n-BuLi gives [{Li(THF)2K(DiepForm)2}n] (2). Preparation of 1 in the presence of chelating ethers or amines gives fully deprotonated polymeric species.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Marcus L. Cole, Aaron J. Davies, Cameron Jones, Peter C. Junk,