Preparation, structure and some chemistry of FcCCCCCCRu(dppe)Cp

The synthesis of Fc(CC)3Ru(dppe)Cp (2) from Fc(CC)3SiMe3 and RuCl(dppe)Cp is described, together with its reactions with tcne to give the tetracyano-dienyl FcCCCC{C[C(CN)2]}2Ru(dppe)Cp (3) and -cyclobutenyl FcCCCC{CCC(CN)2C(CN)2}Ru(dppe)Cp (4), with Co2(μ-dppm)n(CO)8−2n (n = 0, 1) to give FcC2{Co2(CO)6}C2{Co2(CO)6}CCRu(dppe)Cp (5) and FcCCCCC2{Co2(μ-dppm)(CO)4}Ru(dppe)Cp (6), respectively, and with Os3(CO)10(NCMe)2 to give Os3{μ3-C2CCCC[Ru(dppe)Cp]}(CO)10 (7). On standing in solution, the latter isomerises to the cyclo-metallated derivative Os3(μ-H){μ3-C[Ru(dppe)Cp]CCC[(η-C5H3)FeCp]}(CO)8 (8). X-ray structural determinations of 1, 2, 6 and 7 are reported.

Graphical abstractThe synthesis of Fc(CC)3Ru(dppe)Cp (2) from Fc(CC)3SiMe3 and RuCl(dppe)Cp is described, together with its reactions with tcne to give the tetracyano-dienyl FcCCCC{C[C(CN)2]}2Ru(dppe)Cp (3) and -cyclobutenylFcCCCC{CCC(CN)2C(CN)2}Ru(dppe)Cp (4), with Co2(μ-dppm)n(CO)8−2n (n = 0, 1) to give FcC2{Co2(CO)6}C2{Co2(CO)6}CCRu(dppe)Cp (5) and FcCCCCC2{Co2(μ-dppm)(CO)4}Ru(dppe)Cp (6), respectively, and with Os3(CO)10(NCMe)2 to give Os3{μ3-C2CCCC[Ru(dppe)Cp]}(CO)10 (7). On standing in solution, the latter isomerises to the cyclo-metallated derivative Os3(μ-H){μ3-C[Ru(dppe)Cp]CCC[(η-C5H3)FeCp]}(CO)8 (8).Figure optionsDownload full-size imageDownload as PowerPoint slide