| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325348 | Journal of Organometallic Chemistry | 2011 | 4 Pages |
Abstract
A highly thermally stable silylenoid, trisyl(aminomethylphenyl)silylenoid (2) was synthesized from the reaction of dimethylaminomethylphenyllithium with a bromosilylenoid, 1. Silylenoid 2 reacted with electrophiles to give the corresponding products, but did not react with alkyllithiums as a nucleophile.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A highly thermally stable trisyl(aminomethylphenyl)silylenoid was synthesized. ► Our result provides a new synthetic strategy for congested organosilicon compounds. ► This is the first example of a stable silylenoid having intramolecular donor atom.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Hyeon Mo Cho, Young Mook Lim, Byung Wook Lee, Sung Jin Park, Myong Euy Lee,