| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325362 | Journal of Organometallic Chemistry | 2014 | 7 Pages |
Abstract
In this work we report on the synthesis of new [PtCl(η2-CH2=CH2)(NËN)]+ and [PtCl(η1-CH2âCH2OCH3)(NËN)] complexes, with different NËN dinitrogen ligands. The factors determining complex stability are highlighted, and discussed in relation to 1H, 13C and 195Pt NMR chemical shifts exhibited by different complexes bearing hindered or unhindered diamine or diimine ligands.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![[PtCl(η1-CH2-CH2OR)(NËN)] and [PtCl(η2-CH2CH2)(NËN)]+, NËN = dinitrogen ligand, complexes. Sterical and electronic effects evidenced by NMR analysis](/preview/png/1325362.png "First Page Preview: [PtCl(η1-CH2-CH2OR)(NËN)] and [PtCl(η2-CH2CH2)(NËN)]+, NËN = dinitrogen ligand, complexes. Sterical and electronic effects evidenced by NMR analysis")
Authors
Michele Benedetti, Chiara R. Girelli, Daniela Antonucci, Francesco P. Fanizzi,