Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1325416 | Journal of Organometallic Chemistry | 2009 | 4 Pages |
Abstract
Novel PtCl2L2 type complexes (where LÂ =Â 2-diphenylphosphino-malonate derivatives) were prepared and used andas catalytic precursors for the hydroformylation of styrene. High regioselectivities towards branched aldehyde were obtained with all platinum-phosphine-tin(II) chloride catalytic systems. It has been revealed by 31P NMR spectroscopy that the ratio of the cis/trans complexes is strongly dependent on the structure of the ligand.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
György PetÅcz, Gábor Rangits, Megan Shaw, Henriëtte de Bod, D. Bradley G. Williams, László Kollár,