| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325423 | Journal of Organometallic Chemistry | 2009 | 10 Pages |
Abstract
Kinetic studies on the first oxidative addition step of [Rh((C6H5)COCHCOR)(CO)(PPh3)] + CH3I to form [Rh((C6H5)COCHCOR)(CH3)(CO)(PPh3)(I)], R = (CH2)nCH3, n = 1-3, revealed a second order oxidative addition rate constant approximately 500-600 times faster than that observed for the Monsanto catalyst [Rh(CO)2I2]â.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Iodomethane oxidative addition and CO migratory insertion in monocarbonylphosphine complexes of the type [Rh((C6H5)COCHCO((CH2)nCH3))(CO)(PPh3)]: Steric and electronic effects](/preview/png/1325423.png "First Page Preview: Iodomethane oxidative addition and CO migratory insertion in monocarbonylphosphine complexes of the type [Rh((C6H5)COCHCO((CH2)nCH3))(CO)(PPh3)]: Steric and electronic effects")
Authors
Nomampondomise F. Stuurman, Jeanet Conradie,