Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1325439 | Journal of Organometallic Chemistry | 2011 | 8 Pages |
Abstract
⺠Cp2Rh2(CO)3 is predicted to have a singly bridged structure with an Rh-Rh single bond. ⺠Cp2Rh2(CO)2 is predicted to have a doubly bridged structure with an RhRh double bond. ⺠Cp2Rh2(CO) is predicted to have a four-electron donor bridging CO group with an RhRh double bond. ⺠A thermochemically disfavored doubly bridged Cp2Rh2(CO)4 structure with a non-bonding Rh-Rh distance is found.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Xuejun Feng, Limin Chen, Jianyong Lei, Yueshui Jiang, Yaoming Xie, R. Bruce King,