Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1325468 | Journal of Organometallic Chemistry | 2014 | 6 Pages |
•Dinuclear NHC–Pd complexes bridged with diphosphine ligands were synthesized.•All molecular structures have been elucidated by single-crystal X-ray crystallography.•These compounds exhibit high catalytic activities in Buchwald–Hartwig amination.
A series of dinuclear N-heterocyclic carbene (NHC) palladium complexes [PdCl2(NHC)]2(μ-L) (1–6, L = diphosphine ligands) has been synthesized and fully characterized by 1H NMR, 13C NMR and 31P NMR spectroscopies, elemental analysis, IR spectroscopy, and X-ray crystal structural study. The solid-state structures of 1–6 show dinuclear frameworks with two palladium(II) centres were held together by bridging diphosphine ligands. Each palladium centre was coordinated by an N-heterocyclic carbene ligand, a phosphorus atom and two chloro ions in a trans-arrangement. Further explorations of the catalytic potential of the dinuclear carbene palladium complexes as catalysts for Pd-mediated transformations have been examined under microwave irradiation conditions and the title complexes (1–6) displayed good catalytic activities in Buchwald–Hartwig aminations of aryl chlorides.
Graphical abstractA series of dinuclear N-heterocyclic carbene (NHC) palladium complexes have been synthesized and fully characterized. Further explorations of the catalytic potential of the dinuclear carbene palladium complexes as catalysts for Buchwald−Hartwig amination have been tested under microwave irradiation and the complexes displayed good catalytic activities.Figure optionsDownload full-size imageDownload as PowerPoint slide