| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325548 | Journal of Organometallic Chemistry | 2010 | 5 Pages |
Abstract
The reactivity of a uranium dibenzyl complex supported by a ferrocene-diamide ligand toward aromatic N-heterocycles was investigated. Although ring opening occurred, a complicated behavior was observed with 1-methylbenzimidazole and benzoxazole. On the other hand, when a uranium benzyl η2-N,C-benzimidazole complex reacted with quinoline, alkyl transfer to the pyridine ring was observed.
Graphical abstractA uranium benzyl complex supported by a ferrocene-diamide ligand reacts with quinoline by transferring the alkyl ligand to the pyridine ring.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Selma Duhović, Marisa J. Monreal, Paula L. Diaconescu,