| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325619 | Journal of Organometallic Chemistry | 2008 | 7 Pages |
Abstract
A systematic study concerning the transmetalation reaction between the palladium butadienyl complexes [PdCl((ZCCZ)2Me)(L-Lâ²)] (Z = COOMe; L-Lâ²Â = MeN-SPh (1A), N-SPh (1B), DPPQ-Me (1C), BiPy (1D), DPPE (1E)) and tributyl-phenylethynyl-stannane in the presence of some stabilizing olefins (ma, fn, nq, dmfu, and tmetc) was undertaken. The nature of the stabilizing olefin heavily affects the reaction rates which also depend on the donor capability and steric characteristics of the ligands.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Luciano Canovese, Fabiano Visentin, Carlo Levi, Claudio Santo,