| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325691 | Journal of Organometallic Chemistry | 2006 | 7 Pages |
Abstract
The synthesis and characterization of ferrocene-bridged NCN pincer complexes of structural type Fe(η5-C5H4-4-NCN-1-MX)2 (NCN = [C6H2(CH2NMe2)2-2,6]â; X = Cl, I; M = Pd, Pt) is described. Electrochemical measurements show a reversible oxidation of the ferrocene moiety and a dependency of the Fe(II)/Fe(III) potentials towards the presence of the M-halide moieties. The structure in the solid state of one (FePd2) species (6, MX = PdI) is reported as well.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Stefan Köcher, Bernhard Walfort, Gerard P.M. van Klink, Gerard van Koten, Heinrich Lang,