| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325705 | Journal of Organometallic Chemistry | 2006 | 6 Pages |
Abstract
New binuclear nickelacyclic compounds (η5-pentamethylcyclopentadienyl)(η3-(1-(η5-pentamethylcyclopentadienyl))-1-nickelafluorenyl)nickel and (η5-pentamethylcyclopentadienyl)(η3-(1-(η5-pentamethylcyclopentadienyl))-2-phenyl-3-ethyl-1-nickelaindenyl)nickel were synthesised and characterised by high resolution mass spectrometry, magnetic moment determination and X-ray single crystal analysis. The bonding mode of the central nickel atom to the nickelacycles was not η5 like in the previously described analogues of nickelocene but half way between η3 and η5.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Piotr Buchalski, Andrzej KozioÅ, StanisÅaw Pasynkiewicz, Antoni Pietrzykowski, Kinga SuwiÅska, Monika Zdziemborska,