| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325761 | Journal of Organometallic Chemistry | 2013 | 7 Pages |
In the present study, the nickel-catalyzed dehalogenation of aryl and alkyl halides with iso-propyl zinc bromide or tert-butylmagnesium chloride has been examined in detail. With a straightforward nickel complex as pre-catalyst good to excellent yields and chemoselectivities were feasible for a variety of aryl and alkyl halides.
Graphical abstractIn the present study, the nickel-catalyzed dehalogenation of aryl and alkyl halides with iso-propyl zinc bromide or tert-butylmagnesium chloride has been examined in detail. With a straightforward nickel complex as pre-catalyst good to excellent yields and chemoselectivities were feasible for a variety of aryl and alkyl halides.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A novel nickel complex modified by a O, N, O ligand was synthesized. ► The nickel complex was applied as pre-catalyst in the hydrodehalogenation of aryl and alkyl halides. ► Good to excellent yields and chemoselectivities were feasible.
