| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325769 | Journal of Organometallic Chemistry | 2006 | 4 Pages |
Abstract
A two-dimensional polymer, [Tl3(μ-BPC)2(μ-NO3)]n [BPC = biphenyl-2-carboxylate], has been synthesized and characterized. Its single-crystal X-ray structure shows three types of TlI-ions with coordination numbers of 5 (Tl1 and Tl2), and 4 (Tl3). Two of the thallium atoms, Tl1 and Tl3, contain close TlIâ¯Ï (aromatic) contacts, thus attaining a total hapticity of 11 and 10 with environments Tl1O5C6 and Tl3O4C6, respectively.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![TlI2D coordination polymer involving close TlIâ¯Ï (aromatic) contacts, [Tl3(μ-BPC)2(μ-NO3)]n](/preview/png/1325769.png "First Page Preview: TlI2D coordination polymer involving close TlIâ¯Ï (aromatic) contacts, [Tl3(μ-BPC)2(μ-NO3)]n")
Authors
Azadeh Askarinejad, Ali Morsali,