| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325774 | Journal of Organometallic Chemistry | 2006 | 6 Pages |
Abstract
New tetranuclear complexes have been prepared using bridging phosphide or thiolate groups between phosphine gold fragments and the compound [Ru3(CO)9(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCCSiMe3})]. The crystal structures of the intermediates [Ru3(CO)8(NMe3)(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCCSiMe3})] and [Ru3(CO)8(PPh2H)(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCCSiMe3})] have been solved.
Graphical abstractAuPR3 (R = Ph, iPr) fragments have been connected to the ruthenium compound [Ru3(CO)9(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCCSiMe3})], towards phosphide or thiolate bridging groups, affording to new gold–ruthenium complexes.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Gold–ruthenium compounds containing bridging phosphide or thiolate groups: Crystal structures of the intermediate species [Ru3(CO)8L(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCCSiMe3})] (L = NMe3 or PPh2H)](/preview/png/1325774.png "First Page Preview: Gold–ruthenium compounds containing bridging phosphide or thiolate groups: Crystal structures of the intermediate species [Ru3(CO)8L(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCCSiMe3})] (L = NMe3 or PPh2H)")
Authors
Esther Delgado, Elisa Hernández, Miguel A. Maestro, Angel Nievas, Maria Villa,