Article ID Journal Published Year Pages File Type
1325785 Journal of Organometallic Chemistry 2006 14 Pages PDF
Abstract
Oxidative demetalation of Fischer alkoxy carbene complexes with stiochiometric pyridine N-oxide were efficiently realized to generate ester products or stepwisely demetalated products under controlled mild conditions. In the presence of NaBH4, reactions of Fischer iminocarbene complexes with elemental sulfur or selenium regioselectively formed thione or selone derivatives.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Authors
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