Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1325785 | Journal of Organometallic Chemistry | 2006 | 14 Pages |
Abstract
Oxidative demetalation of Fischer alkoxy carbene complexes with stiochiometric pyridine N-oxide were efficiently realized to generate ester products or stepwisely demetalated products under controlled mild conditions. In the presence of NaBH4, reactions of Fischer iminocarbene complexes with elemental sulfur or selenium regioselectively formed thione or selone derivatives.
Related Topics
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Authors
Zhaoyan Zheng, Jinzhu Chen, Zhengkun Yu, Xiuwen Han,