| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325886 | Journal of Organometallic Chemistry | 2010 | 6 Pages |
Abstract
The relatively open edge-bridging bioctahedral structure of the title complex allows its reaction with terminal or internal alkynes under moderate thermal activation to give with good yield products having a propenyl-ylidene ligand bridging the dimetal centre, derived from the coupling of the alkyne to the methoxycarbyne ligand.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Alkyne to carbyne coupling reactions of the unsaturated methoxycarbyne-bridged complex [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(CO)2]](/preview/png/1325886.png "First Page Preview: Alkyne to carbyne coupling reactions of the unsaturated methoxycarbyne-bridged complex [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(CO)2]")
Authors
M. Esther GarcÃa, Daniel GarcÃa-Vivó, Miguel A. Ruiz,