Article ID Journal Published Year Pages File Type
1325888 Journal of Organometallic Chemistry 2010 6 Pages PDF
Abstract

Quantum chemical studies of the reaction of selenium dichloride with divinyl sulfide have been carried out. The major reaction route (2,6-dichloro-1,4-thiaselenane → 5-chloro-2-chloromethyl-1,3-thiaselenolane → 2-chloromethyl-1,3-thiaselenole) and main trends of the reaction (a rearrangement of 2,6-dichloro-1,4-thiaselenane, facile selective dehydrochlorination of 5-chloro-2-chloromethyl-1,3-thiaselenolane), which have been determined by the quantum chemical studies, are in excellent agreement with experimental data.

Graphical abstractQuantum chemical studies of the reaction of selenium dichloride with divinyl sulfide have been carried out. The major reaction route (2,6-dichloro-1,4-thiaselenane → 5-chloro-2-chloromethyl-1,3-thiaselenolane → 2-chloromethyl-1,3-thiaselenole) and main trends of the reaction (a rearrangement of 2,6-dichloro-1,4-thiaselenane, facile selective dehydrochlorination of 5-chloro-2-chloromethyl-1,3-thiaselenolane), which have been determined by the quantum chemical studies, are in excellent agreement with experimental data.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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