| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325892 | Journal of Organometallic Chemistry | 2008 | 4 Pages |
In the presence of CoCl2 · 6H2O, the reaction of TCNE (tetracyanoethylene) with CH3OH forms a dicyanomethylacetate molecule, which has been obtained as one solvent molecule in one new compound {[Co(bpy)2CN2][(NC)2C–CO2CH3]} · 2H2O (1). It was characterized by IR spectra, UV–Vis spectra, and cyclic voltammogram. Its structure was determined by X-ray crystallography: 1 crystallizes in P2(1)/n with a = 13.3368(17), b = 12.5299(16), c = 16.074(2) Å, α = 90, β = 94.6320(10), γ = 90°, and Z = 2.
Graphical abstractIn the presence of CoCl2 · 6H2O, the reaction of TCNE (tetracyanoethylene) with CH3OH forms a dicyanomethylacetate molecule, which has been obtained as one solvent molecule in one new compound {[Co(bpy)2CN2][(NC)2C–CO2CH3]} · 2H2O (1). It was characterized by IR spectra, UV–Vis spectra, and cyclic voltammogram. Its structure was determined by X-ray crystallography: 1 crystallizes in P2(1)/n with a = 13.3368(17), b = 12.5299(16), c = 16.074(2) Å, α = 90, β = 94.6320(10), γ = 90°, and Z = 2.Figure optionsDownload full-size imageDownload as PowerPoint slide
