An experimental and a DFT study on the synthesis, spectroscopic characterization, and reactivity of the adducts of dimethyl- and diphenyltin(IV) dichlorides with γ-pyrones [4H-pyran-4-one (PYR) and 2,6-dimethyl-4H-pyran-4-one (DMP)]: Crystal structure of

The Sn(IV) R2SnCl2(γ-pyrone)n [R = Me or Ph; γ-pyrone = 4H-pyran-4-one (PYR) or 2,6-dimethyl-4H-pyran-4-one (DMP); n = 1 or 2] adducts have been synthesized and investigated. The adducts Ph2SnCl2(PYR) (1), Me2SnCl2(PYR)2 (2), Ph2SnCl2(DMP) (3) and Me2SnCl2(PYR)(PNO) (4), (PNO = 4-methylpyridine N-oxide) have been prepared by the addition of the corresponding γ-pyrone to chloroform solution of R2SnCl2. The new compounds have been characterized by elemental analysis and spectroscopic (IR, 1H, 13C NMR and Mössbauer) means. The single-crystal diffraction study of 1 shows the Sn(IV) to be five-coordinate, [Sn–O and Sn–Cl(1), Sn–Cl(2) distances of 2.3190(13) and 2.4312(6), 2.3653(7), respectively], and the Cl–Sn–Cl bond angle to be 91.17°. The reactivity of 2 towards bipy, Ph3PO, QNO (Q = quinoline) resulted in complete displacement of PYR and formation of already known compounds whereas, the PNO displaced only one equivalent of PYR, causing the preparation of the new mixed complex 4, possibly through a SN1 formation mechanism. DFT/B3LYP molecular orbital calculations were carried out for the 1–4 complexes, their precursors, Ph2SnCl2, (5) and Me2SnCl2, (6) and the ligands, PYR, DMP and PNO in an attempt to explain the structures and reactivity of the complexes. Optimized resulting geometries, vibrational frequencies, and the electron-accepting ability of the complexes and the precursors towards nucleophiles are discussed.

Graphical abstractAn experimental and a DFT theoretical study on the adducts of R2Sn(IV)Cl2 (R = methyl or phenyl) with γ-pyrones (PYR = 4H-pyran-4-one or DMP = 2,6-dimethyl-4H-pyran-4-one). The molecular structure of Ph2SnCl2(PYR) was established by X-ray diffraction analysis, and the reactivity of Me2SnCl2(PYR)2 towards bipy, Ph3PO, QNO (Q = quinoline) was investigated.Figure optionsDownload full-size imageDownload as PowerPoint slide