Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1325914 | Journal of Organometallic Chemistry | 2008 | 7 Pages |
Abstract
Electrochemical data and DFT B3LYP/6-311G calculations suggest that the cation radicals obtained by anodic oxidation of bromobenzyl germatranes retain the endo-configuration; their fast deprotonation allows anodic substitution at the α-position of germatranes. Oxidation Ep are well described by the additive inductive model including mesomeric interactions.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
S. Soualmi, L. Ignatovich, E. Lukevics, A. Ourari, V. Jouikov,