Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1325930 | Journal of Organometallic Chemistry | 2006 | 6 Pages |
Lead (II) phthalocyanine (PbPc); lead (II) tetranitro phthalocyanine (PbTNP) and lead (II) tetraamino phthalocyanine (PbTAP) are synthesized in pure state. These complexes are characterized using elemental analysis, UV–visible, IR-spectroscopy, X-ray crystallography and thermogravimetry. Kinetic and thermodynamic parameters associated with the thermal decomposition were calculated using thermogravimetric data. Electrical conductivity studies are done for all the three complexes using two-probe technique in the temperature range from 30 to 200 °C. The electrical conductivity observed at 30 °C are in the order PbTAP > PbTNP > PbPc. The relevant electrical conductivity data observed are reported.
Graphical abstractLead (II) phthalocyanine (PbPc), lead (II) tetranitro phthalocyanine (PbTNP) and lead (II) tetraamino phthalocyanine (PbTAP) are synthesized in pure state. These complexes are characterized using elemental analysis, UV–visible, IR-spectroscopy, X-ray crystallography and thermogravimetry. Electrical conductivity studies are done for all the three complexes in the temperature range from 30 to 200 °C.Figure optionsDownload full-size imageDownload as PowerPoint slide