Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1325934 | Journal of Organometallic Chemistry | 2006 | 10 Pages |
Abstract
The syntheses of several diynylgold(I) phosphine complexes, including Au(CCCCH){P(tol)3} (1), Au(CCCCSiMe3)(PR3) (R = Ph 2-Ph, tol 2-tol), Au(CCCCFc)(PPh3) (3), {(tol)3P}Au(CC)nAu{P(tol)3} [n = 2 (4), 3 (6), 4 (7)], {(Ph3P)Au}CCCC{Au[P(tol)3]} (5), [ppn][Au{CCCCAu[P(tol)3]}2] (8), [Au2(μ-I)(μ-dppm)2][Au(CCCCSiMe3)2] (9), Hg{CCCCAu(PR3)}2 (R = Ph 10-Ph, tol 10-tol) and {(triphos)Cu}CCCC{Au[P(tol)3]} (11) are described. Of these, the X-ray molecular structures of 1, 2-tol, 3, 4 and 9 have been determined.
Graphical abstractThe synthesis and spectroscopic and structural characterisation of several phosphine–gold(I) complexes containing various diynyl fragments are described.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Michael I. Bruce, Martin Jevric, Brian W. Skelton, Mark E. Smith, Allan H. White, Natasha N. Zaitseva,