| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1325937 | Journal of Organometallic Chemistry | 2006 | 8 Pages |
Abstract
The reaction of Os3(μ-H)(μ-SbPh2)(μ3,η2-C6H4)(CO)9 with AsPh3 afforded the adduct Os3(μ-H)(SbPh2)(μ2,η2-C6H4)(CO)9(AsPh3) and the substitution derivative Os3(μ-H)(SbPh2)(μ3,η2-C6H4)(CO)8(AsPh3). Reaction with tBuNC afforded the adduct Os3(μ-H)(SbPh2)(μ2,η2-C6H4)(CO)9(CNtBu) quantitatively. This adduct isomerised slowly on standing via migration of the isonitrile, while photolysis led to decarbonylation to Os3(μ-H)(SbPh2)(μ2,η2-C6H4)(CO)8(CNtBu).
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Guizhu Chen, Mingli Deng, Chee Keong Don Lee, Weng Kee Leong, Jialin Tan, Chuen Tse Tay,