Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1325941 | Journal of Organometallic Chemistry | 2006 | 11 Pages |
The synthesis of the first series of 4-mono and 3,5-bis(dimethylamino)methyl-functionalized triarylphosphanes of the general formula PPh3 − nArn (Ar = 1-C6H3(CH2NMe2)2-3,5 (NC(H)N), n = 1 (ligand 2) or n = 3 (ligand 4); Ar = 1-C6H4(CH2NMe2)-4 (NC(H)), n = 3 (ligand 7)) is described. These phosphanes were used for the construction of complexes of the form [AuCl(P)] and [PtCl2(P)2]. In these complexes selective coordination of phosphorus to the metal ion is observed. The 31P NMR data show the formation of cis-Pt complexes, even in the case of triarylphosphane 4, which features a tris{3,5-bis(dimethylamino)methyl} substitution pattern. The structure of the gold complex of mono-3,5-functionalized triarylphosphane 2 in the solid state shows a striking resemblance to the structure of the corresponding complex [AuCl(PPh3)]. The solid-state structure of the AuCl complex of tris-4-functionalized ligand 7 differs from that of [AuCl(PPh3)] in the sign of the torsion angles. The amine functionalities in this class of gold compounds could be reacted selectively with either acid (HCl, H3PO4) to generate ammonium salts or with an alkylating agent (benzyl bromide) to afford benzyl ammonium salts, without the violation of the Au–P bond.
Graphical abstractNovel 4-mono and 3,5-bis[(dimethylamino)methyl] functionalized triarylphosphanes have been prepared and used for the construction of complexes of the form [AuCl(P)] and [PtCl2(P)2]. The solution and solid state behavior of these complexes is very similar to that of the corresponding PPh3 complexes. The amine functionalities in the gold compounds have been reacted with either acid (HCl, H3PO4) to generate ammonium salts or with benzyl bromide to afford benzyl ammonium salts, without the violation of the Au–P bond.Figure optionsDownload full-size imageDownload as PowerPoint slide