Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1325979 | Journal of Organometallic Chemistry | 2010 | 4 Pages |
Abstract
[Pt(PPh3)4] reacts smoothly and swiftly at room temperature with asparagusic acid and with selected amide and ester derivatives of this cyclic disulfide to afford PtII dithiolate chelates of the type cis-[Pt{CRR′(CH2S)2}(PPh3)2]. The crystal structures of three such products are reported.
Graphical abstract[Pt(PPh3)4] reacts smoothly and swiftly at room temperature with asparagusic acid and with selected amide and ester derivatives of this cyclic disulfide to afford PtII dithiolate chelates of the type cis-[Pt{CRR′(CH2S)2}(PPh3)2]. The crystal structures of three such products are reported.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ulrich Siemeling, Frauke Bretthauer, Clemens Bruhn,