Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1326022 | Journal of Organometallic Chemistry | 2008 | 10 Pages |
Abstract
The structures and spectroscopic properties of a series of mixed bis-cyclometalated iridium(III) complexes [Ir(ppy)2X2]â (X = CN, 1; X = NCS, 2; X = NCO, 3; ppy = 2-phenylpyridl) were investigated by DFT and ab initio methods. The calculated results showed that the transition character of the absorption and emission can be changed by adjusting the Ï electron-accepting abilities of the X ligands and the phosphorescent color can be tuned by altering the X ligands.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Tao Liu, Hong-Xing Zhang, Bao-Hui Xia,