Article ID Journal Published Year Pages File Type
1326044 Journal of Organometallic Chemistry 2008 4 Pages PDF
Abstract

The manganese(III) complex (2) with a diamide ligand has been synthesized. This complex was found to catalyze both the epoxidation of (Z)- and (E)-stilbene with high conversion and the oxidation of benzyl alcohol to benzaldehyde.

Graphical abstractUsing 2 as catalyst, both (Z)- and (E)-stilbene may be converted to the epoxide in good yield. The mayor products were formed from cis-addition of the oxygen but some of the isomeric epoxide was also formed in each case.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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