Article ID Journal Published Year Pages File Type
1326067 Journal of Organometallic Chemistry 2005 4 Pages PDF
Abstract

α-ω-Dienes bearing a pendant trichloroacetoxy group undergo a tandem RCM – radical cycloisomerization sequence leading to bicyclic γ-butyrolactones, with both steps of the sequence being catalyzed by ruthenium.

Graphical abstractA sequential ring closing metathesis-radical cyclization reaction is described that proceeds in one pot using only one precatalyst.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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