Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1326067 | Journal of Organometallic Chemistry | 2005 | 4 Pages |
Abstract
α-ω-Dienes bearing a pendant trichloroacetoxy group undergo a tandem RCM – radical cycloisomerization sequence leading to bicyclic γ-butyrolactones, with both steps of the sequence being catalyzed by ruthenium.
Graphical abstractA sequential ring closing metathesis-radical cyclization reaction is described that proceeds in one pot using only one precatalyst.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Bernd Schmidt, Michael Pohler,