Synthesis of electron-rich platinum centers: Platinum0(carbene)(alkene)2 complexes

The synthesis and molecular structure of the zero-valent platinum-mono-carbene-bis-alkene complexes [Pt0(NHC)(dimethyl fumarate)2] (NHC = 1,3-dimesityl-imidazol-2-ylidene (1a); 1,3-dimesityl-dihydroimidazol-2-ylidene (2a); diphenyl-dihydroimidazol-2-ylidene (2b) are described. Two routes have been evaluated for the synthesis of 1a and 2a, involving reaction of a zero-valent platinum compound either with an isolated carbene ligand, or with an in situ generated carbene ligand. The in situ method proved to be easier and gave similar yields of about 50% after crystallization. Attempts have been made to synthesize similar compounds with N-phenyl and N-alkyl groups, of which the latter met with little success. However, (1,3-diphenyl-dihydroimidazol-2-ylidene)-bis(η2-dimethyl fumarate) platinum(0) (2b) could be obtained in 49% yield, after crystallization, from the appropriate Wanzlick dimer.Compound 1a reacts with H2 and D2 in sequences of oxidative addition, migration–insertion involving dimethyl fumarate, and reductive elimination to form neutral hydrido platinum (II) carbene complexes, probably containing a metallacyclic (R)–CO … Pt unit.

Graphical abstractSeveral zero-valent platinum-mono-carbene complexes [Pt0(NHC)(dimethyl fumarate)2] (NHC = 1,3-dimesityl-imidazol-2-ylidene; 1,3-dimesityl-dihydroimidazol-2-ylidene; 1,3-diphenyl-dihydroimidazol-2-ylidene) have been synthesized by reaction of platinum(0)-bis(cycloocta-1,5-diene) with the appropriate isolated carbene, or the in situ generated carbene ligand. The synthesis of (1,3-diphenyl-dihydroimidazol-2-ylidene)-bis(η2-dimethyl fumarate) platinum(0) (2b) could be effected from the appropriate Wanzlick dimer. NMR characteristics of the new compounds and their reactions with 1,2,3-trimethyl-imidazolium iodide, with H2 and subsequent insertions and C–H activations are presented.Figure optionsDownload full-size imageDownload as PowerPoint slide