Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1326103 | Journal of Organometallic Chemistry | 2005 | 5 Pages |
Abstract
Here, we report the synthesis of the first phospha-palladacycle substituted with an acyclic carbene. The reaction of bis(dialkyl)aminocarbenes with the very stable phospha-palladacycles leads to metastable η1-carbene complexes, which can be converted by intramolecular reduction to zero valent palladium complexes.
Graphical abstractSynthesis of a phospha-palladacycle substituted with acyclic carbenes, to form metastable η1-carbene complexes, which can be converted to zero valent palladium complexes.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Guido D. Frey, Wolfgang A. Herrmann,