Article ID Journal Published Year Pages File Type
1326161 Journal of Organometallic Chemistry 2010 5 Pages PDF
Abstract
Asymmetrically substituted palladium η3-allyls can be synthesized from tungsten alkoxyvinylcarbenes and a palladium perfluoroaryl complex. The allyls are formed by transmetalation of the carbene fragment followed by migratory insertion of C6F5 to the new and highly reactive Pd carbene complex.
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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Palladium(II) allylic complexes by carbene transmetalation and migratory insertion reactions: Synthesis and side reactions
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